Issue 10, 2014
From the journal:

Dalton Transactions

A novel manganese-doped large polyoxotitanate nanocluster†

Yang Chen,*a   Elzbieta Trzop,a   Anna Makal,ab   Yu-Sheng Chenc  and  Philip Coppens*a  

* Corresponding authors

a Chemistry Department, University at Buffalo, SUNY, Buffalo, New York 14260-3000, USA

b Department of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warszawa, Poland

c ChemMat CARS, University of Chicago, Chicago, Illinois 60637, USA
E-mail: coppens@buffalo.edu, ychen37@buffalo.edu
Fax: +1-716-645-6948
Tel: +1-716-645-4273

Abstract

A large manganese-doped polyoxotitanate nanocluster Ti28MnO38(OEt)40H2, has been synthesized solvothermally. Its structure is arranged around the four-coordinate Mn2+ dopant atom in a Keggin-type structure. A significant reduction of the band gap relative to that of undoped polyoxotitanate clusters is observed.

Graphical abstract: A novel manganese-doped large polyoxotitanate nanocluster

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Article information

DOI
https://doi.org/10.1039/C3DT53416B
Article type
Communication
Submitted
04 Dec 2013
Accepted
14 Jan 2014
First published
15 Jan 2014

Dalton Trans., 2014,43, 3839-3841

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A novel manganese-doped large polyoxotitanate nanocluster

Y. Chen, E. Trzop, A. Makal, Y. Chen and P. Coppens, Dalton Trans., 2014, 43, 3839 DOI: 10.1039/C3DT53416B

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