Issue 19, 2014
From the journal:

Dalton Transactions

‘Auto-click’ functionalization for diversified copper(i) and gold(i) NHCs†

Houssein Ibrahim,a   Clémentine Gibard,a   Cédric Hesling,b   Régis Guillot,c   Laurent Morel,bde   Arnaud Gautier*af  and  Federico Cisnetti*a  

* Corresponding authors

a Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand, France
E-mail: federico.cisnetti@univ-bpclermont.fr

b Clermont Université, Université Blaise Pascal, GReD, BP 10448, F-63000 Clermont-Ferrand, France

c Institut de Chimie Moléculaire et des Matériaux d'Orsay, Bât. 420, Université Paris-Sud, UMR CNRS 8182, F-91405 ORSAY Cedex, France

d CNRS, UMR 6293, GReD, F-63001 Clermont-Ferrand, France

e Inserm, UMR 1103, GReD, F-63001 Clermont-Ferrand, France

f CNRS, UMR 6296, ICCF, F-63171 AUBIERE, France
E-mail: arnaud.gautier@univ-bpclermont.fr

Abstract

Azide-tagged CuI-NHC reacts in an ‘auto-click’ process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting CuI complexes are amenable to further transmetallation to AuI. The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.

Graphical abstract: ‘Auto-click’ functionalization for diversified copper(i) and gold(i) NHCs

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Article information

DOI
https://doi.org/10.1039/C4DT00429A
Article type
Communication
Submitted
10 Feb 2014
Accepted
14 Feb 2014
First published
03 Apr 2014

Dalton Trans., 2014,43, 6981-6989

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‘Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs

H. Ibrahim, C. Gibard, C. Hesling, R. Guillot, L. Morel, A. Gautier and F. Cisnetti, Dalton Trans., 2014, 43, 6981 DOI: 10.1039/C4DT00429A

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