Issue 28, 2014
From the journal:

Dalton Transactions

Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential†

Masafumi Asahi,*a   Shin-ichi Yamazaki,a   Shinobu Itohb  and  Tsutomu Ioroia  

* Corresponding authors

a Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, 1-8-31, Midorigaoka, Ikeda, Osaka 563-8577, Japan
E-mail: m.asahi@aist.go.jp
Fax: +81-72-751-9629
Tel: +81-72-751-9653

b Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka, Japan

Abstract

The CuII/CuI redox properties and electrochemical O2 reduction activity of a series of CuII-complexes with pyridylalkylamine ligands were investigated in a neutral buffer solution. The relationship between CuII/CuI redox properties and O2 reduction activity was clearly demonstrated by voltammetric analyses.

Graphical abstract: Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT00606B
Article type
Communication
Submitted
27 Feb 2014
Accepted
29 May 2014
First published
30 May 2014

Dalton Trans., 2014,43, 10705-10709

Permissions

Request permissions

Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential

M. Asahi, S. Yamazaki, S. Itoh and T. Ioroi, Dalton Trans., 2014, 43, 10705 DOI: 10.1039/C4DT00606B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements