Issue 28, 2014
From the journal:

Dalton Transactions

Gold(iii) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl†

B. David,a   U. Monkowius,b   J. Rust,c   C. W. Lehmann,c   L. Hyzaka  and  F. Mohr*c  

* Corresponding authors

a Fachbereich C, Anorganische Chemie, Bergische Universität Wuppertal, Gaußstr. 20, 42119 Wuppertal, Germany
E-mail: fmohr@uni-wuppertal.de

b Institut für Anorganische Chemie, Johannes Kepler University Linz, Altenbergerstr. 69, 4040 Linz, Austria

c Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

Abstract

An oligomeric gold(III) compound containing dicarbanionic chelating 4,4′-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.

Graphical abstract: Gold(iii) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT00778F
Article type
Paper
Submitted
14 Mar 2014
Accepted
23 May 2014
First published
27 May 2014
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2014,43, 11059-11066

Author version available

Download author version (PDF)

Permissions

Request permissions

Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

B. David, U. Monkowius, J. Rust, C. W. Lehmann, L. Hyzak and F. Mohr, Dalton Trans., 2014, 43, 11059 DOI: 10.1039/C4DT00778F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements