Issue 28, 2014
From the journal:

Dalton Transactions

Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions†

Bemineni Sureshbabu,a   Venkatachalam Ramkumara  and  Sethuraman Sankararaman*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India
E-mail: sanka@iitm.ac.in
Fax: +91 44 22570545
Tel: +91 44 22574210

Abstract

Synthesis of normal and mesoionic N-heterocyclic carbene Pd(II) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.

Graphical abstract: Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions

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Article information

DOI
https://doi.org/10.1039/C4DT01112K
Article type
Communication
Submitted
15 Apr 2014
Accepted
03 Jun 2014
First published
03 Jun 2014

Dalton Trans., 2014,43, 10710-10712

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Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions

B. Sureshbabu, V. Ramkumar and S. Sankararaman, Dalton Trans., 2014, 43, 10710 DOI: 10.1039/C4DT01112K

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