Issue 39, 2014
From the journal:

Dalton Transactions

Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption†

Tony D. Keene,ab   Michael J. Murphy,b   Jason R. Price,bc   Natasha F. Sciortino,b   Peter D. Southon ORCID logo b  and  Cameron J. Kepert*b  

* Corresponding authors

a Chemistry, University of Southampton, University Road, Highfield, Southampton, UK

b School of Chemistry, The University of Sydney, NSW 2006, Australia
E-mail: c.kepert@chem.usyd.edu.au

c Australian Synchrotron Company Limited, 800 Blackburn Road, Clayton, Victoria 3168, Australia

Abstract

The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2·H2O (1·H2O). This compound is a ditopically-bridged copper carbonate kagome lattice where desolvation of the MOF allows subtle tuning of the metamagnetic and uniaxial ZTE behaviour.

Graphical abstract: Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

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Article information

DOI
https://doi.org/10.1039/C4DT02205J
Article type
Paper
Submitted
21 Jul 2014
Accepted
25 Jul 2014
First published
22 Aug 2014

Dalton Trans., 2014,43, 14766-14771

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Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

T. D. Keene, M. J. Murphy, J. R. Price, N. F. Sciortino, P. D. Southon and C. J. Kepert, Dalton Trans., 2014, 43, 14766 DOI: 10.1039/C4DT02205J

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