Issue 44, 2014
From the journal:

Dalton Transactions

Polymorphism dependent light induced spin transition†

Ivan Šalitroš,*ab   Lukáš Pogány,a   Mario Ruben,bc   Roman Bočaad  and  Wolfgang Linerte  

* Corresponding authors

a Department of Inorganic Chemistry (FCHPT), Slovak University of Technology, Bratislava 81237, Slovakia
E-mail: ivan.salitros@stuba.sk

b Institut für Nanotechnologie, Karlsruher Institut für Technologie, 76021 Karlsruhe, Germany

c Institute de Physique et Chimie de Matériaux de Strasbourg (IPCMS), CNRS-Université de Strasbourg, BP 43 67034 Strasbourg Cedex 2, France

d Department of Chemistry (FPV), University of SS Cyril and Methodius, 91701 Trnava, Slovakia

e Institute of Applied Synthetic Chemistry, Vienna University of Technology, A-1060 Vienna, Austria

Abstract

A photomagnetic study of orthorhombic and tetragonal low spin polymorphs of compound [Fe(L)2](BF4)2 revealed different properties and thermal stability of their metastable high spin states. Furthermore, the reversible thermally induced phase/spin transition between low spin and high spin orthorhombic phases was studied by variable temperature UV/VIS spectroscopy.

Graphical abstract: Polymorphism dependent light induced spin transition

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Article information

DOI
https://doi.org/10.1039/C4DT02421D
Article type
Communication
Submitted
08 Aug 2014
Accepted
11 Sep 2014
First published
12 Sep 2014

Dalton Trans., 2014,43, 16584-16587

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Polymorphism dependent light induced spin transition

I. Šalitroš, L. Pogány, M. Ruben, R. Boča and W. Linert, Dalton Trans., 2014, 43, 16584 DOI: 10.1039/C4DT02421D

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