Structural and magnetic variations in tetranuclear NiII clusters: the effect of the reaction solvent and ligand substitution on product identity

Panagiota S. Perlepe; Angeliki A. Athanasopoulou; Konstantina I. Alexopoulou; Catherine P. Raptopoulou; Vassilis Psycharis; Albert Escuer; Spyros P. Perlepes; Theocharis C. Stamatatos

doi:10.1039/C4DT02434F

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Structural and magnetic variations in tetranuclear Ni^II clusters: the effect of the reaction solvent and ligand substitution on product identity†

Panagiota S. Perlepe,^ab Angeliki A. Athanasopoulou,^a Konstantina I. Alexopoulou,^b Catherine P. Raptopoulou,^c Vassilis Psycharis,^c Albert Escuer,^d Spyros P. Perlepes*^b and Theocharis C. Stamatatos*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, 500 Glenridge Ave, Brock University, L2S 3A1 St. Catharines, Ontario, Canada
E-mail: tstamatatos@brocku.ca

^b Department of Chemistry, University of Patras, 265 04 Patras, Greece

^c Institute of Advanced Materials, Physicochemical Processes, Nanotechnology and Microsystems, NCSR “Demokritos”, 153 10 Agia Paraskevi Attikis, Greece

^d Departament de Quimica Inorganica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

Abstract

Three structurally and magnetically different tetranuclear Ni^II complexes have been isolated and magnetically characterized, emphasizing the effect of the reaction solvent and organic ligand substitution on the chemical identity of cluster compounds.

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Article information

DOI: https://doi.org/10.1039/C4DT02434F
Article type: Communication
Submitted: 10 Aug 2014
Accepted: 19 Sep 2014
First published: 19 Sep 2014

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Dalton Trans., 2014,43, 16605-16609

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Structural and magnetic variations in tetranuclear Ni^II clusters: the effect of the reaction solvent and ligand substitution on product identity

P. S. Perlepe, A. A. Athanasopoulou, K. I. Alexopoulou, C. P. Raptopoulou, V. Psycharis, A. Escuer, S. P. Perlepes and T. C. Stamatatos, Dalton Trans., 2014, 43, 16605 DOI: 10.1039/C4DT02434F

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Dalton Transactions