Herein, we describe a copper-free, oxidant-free, solvent-free homocoupling reaction using a palladium catalyst under mechanochemical conditions. We extended the methodology to palladium catalyst on solid support which showed a different reactivity and different product ratios from the non-supported catalyst. We were able to recycle the polymer supported catalyst for 5 cycles.
L. Chen, B. E. Lemma, J. S. Rich and J. Mack, Green Chem., 2014, 16, 1101 DOI: 10.1039/C3GC41847B
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