Issue 3, 2014
From the journal:

Green Chemistry

A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(i) complexes†

José G. Hernández,a   Neil A. J. Macdonald,a   Cristina Mottillo,a   Ian S. Butler*a  and  Tomislav Friščić*a  

* Corresponding authors

a Department of Chemistry and FRQNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. W, Canada
E-mail: tomislav.friscic@mcgill.ca, ian.butler@mcgill.ca

Abstract

A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.

Graphical abstract: A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(i) complexes

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Article information

DOI
https://doi.org/10.1039/C3GC42104J
Article type
Communication
Submitted
10 Oct 2013
Accepted
07 Nov 2013
First published
08 Nov 2013

Green Chem., 2014,16, 1087-1092

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A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re(I) complexes

J. G. Hernández, N. A. J. Macdonald, C. Mottillo, I. S. Butler and T. Friščić, Green Chem., 2014, 16, 1087 DOI: 10.1039/C3GC42104J

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