Formation of C–C bonds for the production of bio-alkanes under mild conditions

Abstract

It is of crucial importance to form C–C bonds between biomass-derived compounds for the production of bio-alkanes from biomass. In this study, it was found that C–C bonds can be formed between angelica lactones, key intermediates derived from biomass, through free radical reactions under mild conditions without using a noble catalyst or solvent, which gave elongated carbon chains of di/trimers with 10 or 15 carbons, with complete conversion and 100% selectivity. The di/trimers produced serve as a novel feedstock for the carbon backbones of bio-alkanes. Hydrogenation of the di/trimers produced C6–C13 hydrocarbons suitable for use as transportation fuels.