The synthesis of a range of novel silyl-protected dioxaborinanes as a column- and bench-stable boron reagent were found to be advantageous to achieving good yields in palladium-catalysed cross-coupling reactions under standard conditions.
S. Goggins, E. Rosevere, C. Bellini, J. C. Allen, B. J. Marsh, M. F. Mahon and C. G. Frost, Org. Biomol. Chem., 2014, 12, 47 DOI: 10.1039/C3OB42099J
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