Issue 10, 2014
From the journal:

Organic & Biomolecular Chemistry

Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst†

Ming Yu Jin,‡a   Sun Min Kim,‡b   Hui Mao,b   Do Hyun Ryu,a   Choong Eui Songa  and  Jung Woon Yang*b  

* Corresponding authors

a Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Republic of Korea

b Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Republic of Korea
E-mail: jwyang@skku.edu
Fax: +82-31-299-4279
Tel: +82-31-299-4276

Abstract

We found that chemoselectivity of the crossed acyloin product is controlled by the adjustment of the aromatic aldehyde/aliphatic aldehyde ratio. Moreover, we observed the persistent catalytic activity of the homogeneous NHC catalyst in a solution due to NHC catalyst robustness.

Graphical abstract: Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

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Article information

DOI
https://doi.org/10.1039/C3OB42486C
Article type
Communication
Submitted
12 Dec 2013
Accepted
06 Jan 2014
First published
07 Jan 2014

Org. Biomol. Chem., 2014,12, 1547-1550

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Chemoselective and repetitive intermolecular cross-acyloin condensation reactions between a variety of aromatic and aliphatic aldehydes using a robust N-heterocyclic carbene catalyst

M. Y. Jin, S. M. Kim, H. Mao, D. H. Ryu, C. E. Song and J. W. Yang, Org. Biomol. Chem., 2014, 12, 1547 DOI: 10.1039/C3OB42486C

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