Issue 38, 2014
From the journal:

Organic & Biomolecular Chemistry

A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(iii)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide†

Jie Shenga  and  Jie Wu*ab  

* Corresponding authors

a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China
E-mail: jie_wu@fudan.edu.cn
Fax: +8621 6564 1740
Tel: +86 21 6510 2412

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China

Abstract

A bismuth(III)-promoted reaction of trimethyl(alkynyl)silanes with trifluoromethanesulfanylamide is developed, giving rise to (alkynyl)(trifluoromethyl)sulfanes in good yields.

Graphical abstract: A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(iii)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

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Article information

DOI
https://doi.org/10.1039/C4OB01451K
Article type
Paper
Submitted
10 Jul 2014
Accepted
06 Aug 2014
First published
06 Aug 2014

Org. Biomol. Chem., 2014,12, 7629-7633

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A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(III)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide

J. Sheng and J. Wu, Org. Biomol. Chem., 2014, 12, 7629 DOI: 10.1039/C4OB01451K

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