A versatile method for the preparation of aryldifluoromethylphosphonates has been developed. This represents the first example of copper-catalyzed difluoroalkylation of ArBr and provides a useful and facile access to diverse aryldifluoromethylphosphonates that are difficult to prepare otherwise.
Z. Feng, Y. Xiao and X. Zhang, Org. Chem. Front., 2014, 1, 113 DOI: 10.1039/C3QO00044C
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