Issue 2, 2014
From the journal:

Organic Chemistry Frontiers

Chiral spiro iridium catalysts with SpiroPAP ligands: highly efficient for asymmetric hydrogenation of ketones and ketoesters

Xiao-Hui Yang,a   Jian-Hua Xie*a  and  Qi-Lin Zhou*a  

* Corresponding authors

a State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, China
E-mail: jhxie@nankai.edu.cn, qlzhou@nankai.edu.cn
Fax: +86 22 2350 6177
Tel: +86 22 2350 0011

Abstract

This tutorial account describes the design of chiral spiro iridium catalysts bearing spiro pyridine–aminophosphine ligands, and their preparation and application in the asymmetric hydrogenation of ketones and β-aryl-β-ketoesters.

Graphical abstract: Chiral spiro iridium catalysts with SpiroPAP ligands: highly efficient for asymmetric hydrogenation of ketones and ketoesters

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Article information

DOI
https://doi.org/10.1039/C3QO00056G
Article type
Tutorial Account
Submitted
26 Nov 2013
Accepted
19 Dec 2013
First published
16 Jan 2014

Org. Chem. Front., 2014,1, 190-193

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Chiral spiro iridium catalysts with SpiroPAP ligands: highly efficient for asymmetric hydrogenation of ketones and ketoesters

X. Yang, J. Xie and Q. Zhou, Org. Chem. Front., 2014, 1, 190 DOI: 10.1039/C3QO00056G

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