P(O)R2 directed Pd(II)-catalyzed C(sp2)–H acylation

Yan-Na Ma; Qiu-Ping Tian; Hong-Yu Zhang; An-Xi Zhou; Shang-Dong Yang

doi:10.1039/C4QO00005F

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P(O)R₂ directed Pd(ii)-catalyzed C(sp²)–H acylation†

Yan-Na Ma,^a Qiu-Ping Tian,^a Hong-Yu Zhang,^a An-Xi Zhou^a and Shang-Dong Yang*^ab

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* Corresponding authors

^a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
E-mail: yangshd@lzu.edu.cn
Fax: +86-931-8912859
Tel: +86-931-8912859

^b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000, P. R. China

Abstract

A novel method for the Pd(II)-catalyzed C–H acylation of 2-phosphorylbiphenyl with α-oxocarboxylic acids, aldehydes, alcohols and toluene is described. This reaction provides efficient access to various substituted 2′-phosphorylbiphenyl-2-acyl compounds.

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Article information

DOI: https://doi.org/10.1039/C4QO00005F
Article type: Research Article
Submitted: 07 Jan 2014
Accepted: 17 Feb 2014
First published: 05 Mar 2014

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Org. Chem. Front., 2014,1, 284-288

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P(O)R₂ directed Pd(II)-catalyzed C(sp²)–H acylation

Y. Ma, Q. Tian, H. Zhang, A. Zhou and S. Yang, Org. Chem. Front., 2014, 1, 284 DOI: 10.1039/C4QO00005F

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