Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates

Irene R. Márquez; Alba Millán; Araceli G. Campaña; Juan M. Cuerva

doi:10.1039/C4QO00012A

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Cp₂TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates†

Irene R. Márquez,^a Alba Millán,^a Araceli G. Campaña*^a and Juan M. Cuerva*^a

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* Corresponding authors

^a Organic Chemistry Department, University of Granada, C/Severo Ochoa, S/N, Granada, Spain
E-mail: jmcuerva@ugr.es, araceligc@ugr.es
Fax: +31 958 243320
Tel: +31 958 243319

Abstract

A useful method for the diastereoselective synthesis of vinyl substituted carbo- and heterocycles is described. Highly functionalized structures difficult to achieve by other methodologies are obtained in a single step by this procedure.

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Article information

DOI: https://doi.org/10.1039/C4QO00012A
Article type: Research Article
Submitted: 14 Jan 2014
Accepted: 17 Feb 2014
First published: 18 Mar 2014
This article is Open Access

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Org. Chem. Front., 2014,1, 373-381

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Cp₂TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates

I. R. Márquez, A. Millán, A. G. Campaña and J. M. Cuerva, Org. Chem. Front., 2014, 1, 373 DOI: 10.1039/C4QO00012A

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