Issue 6, 2014
From the journal:

Organic Chemistry Frontiers

Palladium-catalyzed heteroannulation of [60]fullerene with N-(2-arylethyl) sulfonamides via C–H bond activation†

Yi-Tan Su,a   You-Liang Wanga  and  Guan-Wu Wang*ab  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: gwang@ustc.edu.cn

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, P. R. China

Abstract

The palladium-catalyzed heteroannulation of [60]fullerene with various N-(2-arylethyl) sulfonamides afforded a variety of [60]fullerene-fused tetrahydrobenzazepines. These reactions were initiated by C–H bond activation and followed by cyclization. In addition, further transformation and electrochemistry of the obtained [60]fullerene-fused tetrahydrobenzazepines were investigated.

Graphical abstract: Palladium-catalyzed heteroannulation of [60]fullerene with N-(2-arylethyl) sulfonamides via C–H bond activation

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Article information

DOI
https://doi.org/10.1039/C4QO00106K
Article type
Research Article
Submitted
03 Apr 2014
Accepted
27 May 2014
First published
28 May 2014

Org. Chem. Front., 2014,1, 689-693

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Palladium-catalyzed heteroannulation of [60]fullerene with N-(2-arylethyl) sulfonamides via C–H bond activation

Y. Su, Y. Wang and G. Wang, Org. Chem. Front., 2014, 1, 689 DOI: 10.1039/C4QO00106K

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