Issue 10, 2014
From the journal:

Organic Chemistry Frontiers

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts†‡

Gaoyuan Maa  and  Mukund P. Sibi*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108, USA
E-mail: mukund.sibi@ndsu.edu

Abstract

We have investigated the asymmetric allylic amination of Morita–Baylis–Hillman (MBH) carbonates with nitrogen nucleophiles in the presence of newly designed chiral DMAP catalysts. A series of α-methylene β-amino esters were obtained with good yield and selectivities.

Graphical abstract: Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4QO00210E
Article type
Research Article
Submitted
26 Jul 2014
Accepted
09 Sep 2014
First published
10 Sep 2014

Org. Chem. Front., 2014,1, 1152-1156

Permissions

Request permissions

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

G. Ma and M. P. Sibi, Org. Chem. Front., 2014, 1, 1152 DOI: 10.1039/C4QO00210E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements