A strategy for the synthesis of synthetically useful benzoxasilole derivatives by combining a gold(I) complex/Brønsted acid binary system and a temporary silicon tether method has been developed that involves relay catalytic cascade intramolecular allylation of alkynes by a gold(I) complex and addition of silanols to enones by a Brønsted acid.
Y. Horino, Y. Takahashi, Y. Nakashima and H. Abe, RSC Adv., 2014, 4, 6215 DOI: 10.1039/C3RA47149G
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