Issue 17, 2014

Tailoring porosities and electrochemical properties of composites composed of microfibrillated cellulose and polypyrrole

Abstract

Composites of polypyrrole and nanocellulose (PPy/nanocellulose) have a high potential as electrodes in energy-storage devices and as membranes for electrochemically controlled ion-exchange systems. In the present work, it is demonstrated that such composites with 42–72% porosity can be produced by using microfibrillated cellulose (MFC) prepared through enzymatic pretreatment or carboxymethylation, or by using different amounts of MFC in the composite synthesis. Together with previous work, this shows that the porosity of PPy/nanocellulose composites can be tailored from 30 to 98% with increments of ∼10%. Employing the full porosity range of the composites, it is demonstrated that the electrochemical oxidation rate of the materials depends on their porosity due to limitations in the counter ion diffusion process. By tailoring the porosities of PPy/nanocellulose composites, the electrochemical properties can consequently be controlled. The latter provides new possibilities for the manufacturing of electrochemically controlled ion-extraction and energy storage devices with optimized volumetric energy and power densities.

Graphical abstract: Tailoring porosities and electrochemical properties of composites composed of microfibrillated cellulose and polypyrrole

Article information

Article type
Paper
Submitted
12 Dec 2013
Accepted
14 Jan 2014
First published
16 Jan 2014

RSC Adv., 2014,4, 8489-8497

Author version available

Tailoring porosities and electrochemical properties of composites composed of microfibrillated cellulose and polypyrrole

D. O. Carlsson, A. Mihranyan, M. Strømme and L. Nyholm, RSC Adv., 2014, 4, 8489 DOI: 10.1039/C3RA47588C

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