Issue 28, 2014
From the journal:

RSC Advances

Stereoselective inversion of γ-vinyl-γ-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins†

Rodney A. Fernandes,*a   Pullaiah Kattangurua  and  Venkati Bethia  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, Maharashtra, India
E-mail: rfernand@chem.iitb.ac.in
Fax: +91-22-25767152
Tel: +91-22-25767174

Abstract

An efficient γ-epimerization of γ-vinyl-γ-butyrolactone is studied under palladium catalysis. The building blocks derived there in are used in an efficient stereoselective synthesis of (+)-exo- and (+)-endo-brevicomins.

Graphical abstract: Stereoselective inversion of γ-vinyl-γ-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins

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Article information

DOI
https://doi.org/10.1039/C4RA00814F
Article type
Paper
Submitted
28 Jan 2014
Accepted
04 Mar 2014
First published
11 Mar 2014

RSC Adv., 2014,4, 14507-14512

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Stereoselective inversion of γ-vinyl-γ-butyrolactone under palladium catalysis: application to the synthesis of (+)-exo- and (+)-endo-brevicomins

R. A. Fernandes, P. Kattanguru and V. Bethi, RSC Adv., 2014, 4, 14507 DOI: 10.1039/C4RA00814F

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