Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

Abstract

Fatty acid-based bis-cyclic 5-membered carbonates containing amide linkages were prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates with a series of di-amines led to poly(hydroxyurethane amide)s with molar masses up to 31 000 g mol⁻¹. As expected, the so-formed bio-based thermoplastic poly(hydroxyurethane)s exhibit amorphous to semi-crystalline features with respect to the chemical structure of the monomers used.