Issue 101, 2014
From the journal:

RSC Advances

Pd@Pt/C catalysts fabricated using chemisorbed CO as in situ reductant: advanced catalytic behaviour for formic acid oxidation†

Shikui Yao,ab   Guoqiang Li,ab   Meiling Xiao,ab   Junjie Ge,c   Changpeng Liu*d  and  Wei Xing*a  

* Corresponding authors

a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: xingwei@ciac.ac.cn
Tel: +86-431-85262223

b University of Chinese Academy of Sciences, Beijing, China

c Hawaii Natural Energy Institute, University of Hawaii, Manoa, 1680 East-West Road, POST 109, Honolulu, HI 96822, USA

d Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: liuchp@ciac.ac.cn
Tel: +86-431-85262225

Abstract

A Pd sub-layer on a Pt substrate is fabricated stoichiometrically using chemisorbed CO as an in situ reductant. The Pd sub-layer of the Pd@Pt/C catalysts exhibits a more negative oxidation peak and 3 times higher mass activity for formic acid oxidation than commercial Pd/C.

Graphical abstract: Pd@Pt/C catalysts fabricated using chemisorbed CO as in situ reductant: advanced catalytic behaviour for formic acid oxidation

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C4RA11121D
Article type
Communication
Submitted
24 Sep 2014
Accepted
28 Oct 2014
First published
29 Oct 2014

RSC Adv., 2014,4, 57819-57822

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Pd@Pt/C catalysts fabricated using chemisorbed CO as in situ reductant: advanced catalytic behaviour for formic acid oxidation

S. Yao, G. Li, M. Xiao, J. Ge, C. Liu and W. Xing, RSC Adv., 2014, 4, 57819 DOI: 10.1039/C4RA11121D

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