Issue 109, 2014
From the journal:

RSC Advances

Palladium-catalyzed carbonylation of allylamines via C–N bond activation leading to β,γ-unsaturated amides†

Hui Yu,a   Guoying Zhang,b   Zong-Jian Liu*a  and  Hanmin Huang*ab  

* Corresponding authors

a College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310024, China
E-mail: zjliu@zjut.edu.cn

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
E-mail: hmhuang@licp.cas.cn

Abstract

Pd(Xantphos)Cl2 has been identified as an efficient catalyst for the direct carbonylation of allylamines via C–N bond activation. The reaction proceeds smoothly and provides β,γ-unsaturated amides in good to excellent yields under relatively mild conditions.

Graphical abstract: Palladium-catalyzed carbonylation of allylamines via C–N bond activation leading to β,γ-unsaturated amides

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Article information

DOI
https://doi.org/10.1039/C4RA13939A
Article type
Communication
Submitted
14 Oct 2014
Accepted
19 Nov 2014
First published
19 Nov 2014

RSC Adv., 2014,4, 64235-64237

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Palladium-catalyzed carbonylation of allylamines via C–N bond activation leading to β,γ-unsaturated amides

H. Yu, G. Zhang, Z. Liu and H. Huang, RSC Adv., 2014, 4, 64235 DOI: 10.1039/C4RA13939A

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