Sandwich-structured graphene–NiFe2O4–carbon nanocomposite anodes with exceptional electrochemical performance for Li ion batteries

Abstract

Graphene–NiFe₂O₄–carbon nanocomposites with a sandwich structure are synthesized via the hydrothermal growth of NiFe₂O₄ nanoparticles on graphene sheets, followed by carbon coating. As a promising anode material for Li ion batteries, the nanocomposites deliver exceptional cycle stability of 1195 mA h g⁻¹ after 200 cycles measured at 500 mA g⁻¹. This value is among the highest reported so far for anodes containing similar NiFe₂O₄ nanoparticles. The synergy arising from the conductive graphene substrate, the well-dispersed, ultrafine NiFe₂O₄ nanoparticles and the protective carbon layer sustaining the sandwich together is responsible for this trait.