Prediction of analytes' electrophoretic mobility in mixed solvent buffers using Abraham solvation parameters

Abstract

The electrophoretic mobility of analytes in different solvent compositions of the background electrolyte was calculated using a combined version of a previously developed model with the Abraham solvation model for providing predictive equations. These equations could be used in capillary zone electrophoresis method development studies. Good agreements between predicted and experimental mobility data were obtained.