Hemoglobin- and catalase-polymerized PEDOT:PSS were characterized by X-ray photoelectron spectroscopy, visible and near-IR spectroscopy, FTIR, and ESR. Hemoglobin-polymerized PEDOT:PSS possesses bipolarons, while catalase-polymerized PEDOT:PSS is dominated by polarons. Use of heme-bound iron as an oxidant yields PEDOT:PSS with conductivity of 19.5 S cm−1 in a single-step aqueous reaction.
J. D. Morris, D. Khanal, J. A. Richey and C. K. Payne, Biomater. Sci., 2015, 3, 442 DOI: 10.1039/C4BM00338A
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