Issue 39, 2015

A novel carbamoyl radical based dearomatizing spiroacylation process

Abstract

An easy access to novel spirodienonamides based on a dearomatizing spiroacylation process is described for the first time. This process was realized using carbamoylxanthates which were transformed into spirodienonamides containing an acyl-functionalized all-carbon quaternary center.

Graphical abstract: A novel carbamoyl radical based dearomatizing spiroacylation process

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2014
Accepted
03 Apr 2015
First published
08 Apr 2015

Chem. Commun., 2015,51, 8345-8348

Author version available

A novel carbamoyl radical based dearomatizing spiroacylation process

A. Millán-Ortiz, G. López-Valdez, F. Cortez-Guzmán and L. D. Miranda, Chem. Commun., 2015, 51, 8345 DOI: 10.1039/C4CC06192F

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