A spacer-bridged bis(organostannylene) was obtained. In the solid-state it adopts the structure of a doubly-capped tetrahedron. It reacts with elemental oxygen, O2, giving tin suboxides. Additionally, the first solid state structure of a spacer-bridged diorgano tin dihydride is reported.
![Graphical abstract: [Me2C{SnCH(SiMe3)2}2]2. A μ-Me2C-bridged tetrastanna tetrahedrane](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC07417C&imageInfo.ImageIdentifier.Year=2015)
M. Wagner, M. Lutter, B. Zobel, W. Hiller, M. H. Prosenc and K. Jurkschat, Chem. Commun., 2015, 51, 153 DOI: 10.1039/C4CC07417C
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