The reversible binding of xenon to cryptophane molecules is currently heavily explored for application as a reporter system in NMR. Herein, for aqueous solution, first evidence of degenerate exchange in this host–guest system is presented based on a novel approach using hyperpolarized 129Xe.
S. Korchak, W. Kilian and L. Mitschang, Chem. Commun., 2015, 51, 1721 DOI: 10.1039/C4CC08601E
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