Issue 12, 2015
From the journal:

Chemical Communications

A host–guest inclusion compound for reversible switching of quadratic nonlinear optical properties†

Chengmin Ji,a   Zhihua Sun,a   Shuquan Zhang,a   Sangen Zhao,a   Tianliang Chen,a   Yuanyuan Tanga  and  Junhua Luo*a  

* Corresponding authors

a Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P.R. China
E-mail: jhluo@fjirsm.ac.cn
Fax: +86 591 83730955
Tel: +86 591 83730955

Abstract

A host–guest inclusion compound [(DPA)(18-crown-6)]ClO4 (DPA = dipropylamine) undergoes a reversible phase transition at 214 K, which enables it to switch the NLO response between SHG-ON and SHG-OFF states associated with the order–disorder transition of the guest DPA cations and a slight tilting of the host 18-crown-6 molecules.

Graphical abstract: A host–guest inclusion compound for reversible switching of quadratic nonlinear optical properties

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Article information

DOI
https://doi.org/10.1039/C4CC08711A
Article type
Communication
Submitted
02 Nov 2014
Accepted
18 Dec 2014
First published
18 Dec 2014

Chem. Commun., 2015,51, 2298-2300

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A host–guest inclusion compound for reversible switching of quadratic nonlinear optical properties

C. Ji, Z. Sun, S. Zhang, S. Zhao, T. Chen, Y. Tang and J. Luo, Chem. Commun., 2015, 51, 2298 DOI: 10.1039/C4CC08711A

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