Issue 10, 2015
From the journal:

Chemical Communications

Ethylaluminum as an ethylene source for the Mizoroki–Heck-type reaction. Rhodium-catalyzed preparation of stilbene derivatives†

Shota Tanaka,a   Kazuki Itami,a   Kazuhiro Sunahara,a   Go Tatsutaa  and  Atsunori Mori*a  

* Corresponding authors

a Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501, Japan
E-mail: amori@kobe-u.ac.jp
Fax: +81-78-803-6181
Tel: +81-78-803-6181

Abstract

Treatment of an organoaluminum reagent bearing aryl and ethyl groups furnishes 1,2-diarylethene derivatives in good to excellent yields by the catalysis of a rhodium complex, in which the ethyl group of the aluminum reagent serves as an ethylene source in the product formation.

Graphical abstract: Ethylaluminum as an ethylene source for the Mizoroki–Heck-type reaction. Rhodium-catalyzed preparation of stilbene derivatives

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Article information

DOI
https://doi.org/10.1039/C4CC09306B
Article type
Communication
Submitted
21 Nov 2014
Accepted
11 Dec 2014
First published
15 Dec 2014

Chem. Commun., 2015,51, 1949-1952

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Ethylaluminum as an ethylene source for the Mizoroki–Heck-type reaction. Rhodium-catalyzed preparation of stilbene derivatives

S. Tanaka, K. Itami, K. Sunahara, G. Tatsuta and A. Mori, Chem. Commun., 2015, 51, 1949 DOI: 10.1039/C4CC09306B

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