Issue 15, 2015
From the journal:

Chemical Communications

Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(ii)-framework†

Susan Sen,a   Subhadip Neogi,a   Kari Rissanenb  and  Parimal K. Bharadwaj*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kanpur 208016, India
E-mail: pkb@iitk.ac.in
Fax: (+91) 512-259-7436
Tel: (+91) 512-259-7034

b Department of Chemistry, NanoScience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä, Finland
E-mail: kari.t.rissanen@jyu.fi

Abstract

A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.

Graphical abstract: Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(ii)-framework

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Article information

DOI
https://doi.org/10.1039/C4CC09955A
Article type
Communication
Submitted
13 Dec 2014
Accepted
02 Jan 2015
First published
05 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3173-3176

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Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework

S. Sen, S. Neogi, K. Rissanen and P. K. Bharadwaj, Chem. Commun., 2015, 51, 3173 DOI: 10.1039/C4CC09955A

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