Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67

William Salomon; Catherine Roch-Marchal; Pierre Mialane; Paul Rouschmeyer; Christian Serre; Mohamed Haouas; Francis Taulelle; Shu Yang; Laurent Ruhlmann; Anne Dolbecq

doi:10.1039/C4CC09986A

Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67†

William Salomon,^a Catherine Roch-Marchal,*^a Pierre Mialane,^a Paul Rouschmeyer,^a Christian Serre,^a Mohamed Haouas,^a Francis Taulelle,^a Shu Yang,^b Laurent Ruhlmann^b and Anne Dolbecq*^a

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^a Institut Lavoisier de Versailles, UMR 8180, Université de Versailles Saint-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles cedex, France
E-mail: catherine.roch@uvsq.fr, anne.dolbecq@uvsq.fr

^b Université de Strasbourg, Institut de Chimie, UMR CNRS 7177, Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, 4 rue Blaise Pascal, CS 90032, 67081 Strasbourg cedex, France

Abstract

The encapsulation of polyoxometalates within the large pores of the Zr(IV) biphenyldicarboxylate UiO-67 metal–organic framework has been achieved, for the first time, by direct solvothermal synthesis. The resulting POM@UiO-67 composite materials were fully characterized by XRPD, IR, MAS NMR, N₂ porosimetry measurements and cyclic voltammetry.

Chemical Communications

Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67†

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Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67

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