Issue 14, 2015
From the journal:

Chemical Communications

Regioselective electrophilic borylation of haloarenes†

Alessandro Del Grosso,a   Josue Ayuso Carrillo ORCID logo a  and  Michael J. Ingleson*a  

* Corresponding authors

a School of Chemistry, University of Manchester, Manchester, UK
E-mail: Michael.ingleson@manchester.ac.uk

Abstract

Haloarenes undergo direct borylation using amine : BCl3 : AlCl3 in the ratio of 1 : 1 : 2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

Graphical abstract: Regioselective electrophilic borylation of haloarenes

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Article information

DOI
https://doi.org/10.1039/C4CC10153G
Article type
Communication
Submitted
19 Dec 2014
Accepted
02 Jan 2015
First published
05 Jan 2015

Chem. Commun., 2015,51, 2878-2881

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Regioselective electrophilic borylation of haloarenes

A. Del Grosso, J. Ayuso Carrillo and M. J. Ingleson, Chem. Commun., 2015, 51, 2878 DOI: 10.1039/C4CC10153G

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