A diastereoselective Pd-catalyzed intramolecular cyclopropanation of alkenes with unstabilized allylic tosylhydrazones was developed. This methodology provides an efficient entry toward synthesis of the bicyclo[3.1.0] hexane system with an exo-double bond, and sets the basis for future elaboration of more complex polycyclic motifs.
Y. Yang, J. Li, B. Du, C. Yuan, B. Liu and S. Qin, Chem. Commun., 2015, 51, 6179 DOI: 10.1039/C5CC00235D
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