Issue 24, 2015
From the journal:

Chemical Communications

Iron-catalyzed asymmetric hydrosilylation of ketones†

Ziqing Zuo,a   Lei Zhang,a   Xuebing Lenga  and  Zheng Huang*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032, China
E-mail: huangzh@sioc.ac.cn
Fax: + 86 5492 5533
Tel: + 86 5492 5522

Abstract

A series of iron complexes of chiral iminopyridine-oxazoline (IPO) ligands have been synthesized. The most sterically hindered iron catalyst exhibits excellent activity (up to 99% yield) and high enantioselectivity (up to 93% ee) in asymmetric hydrosilylation of aryl ketones.

Graphical abstract: Iron-catalyzed asymmetric hydrosilylation of ketones

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Article information

DOI
https://doi.org/10.1039/C5CC00612K
Article type
Communication
Submitted
22 Jan 2015
Accepted
16 Feb 2015
First published
16 Feb 2015

Chem. Commun., 2015,51, 5073-5076

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Iron-catalyzed asymmetric hydrosilylation of ketones

Z. Zuo, L. Zhang, X. Leng and Z. Huang, Chem. Commun., 2015, 51, 5073 DOI: 10.1039/C5CC00612K

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