Na2B10O17·H2en: a three-dimensional open-framework layered borate co-templated by inorganic cations and organic amines

Jun-Hua Wang; Qi Wei; Jian-Wen Cheng; Huan He; Bai-Feng Yang; Guo-Yu Yang

doi:10.1039/C5CC00800J

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Na₂B₁₀O₁₇·H₂en: a three-dimensional open-framework layered borate co-templated by inorganic cations and organic amines†

Jun-Hua Wang,^a Qi Wei,^c Jian-Wen Cheng,*^b Huan He,^a Bai-Feng Yang^a and Guo-Yu Yang*^ac

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Cluster Science, Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
E-mail: ygy@bit.edu.cn

^b Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
E-mail: jwcheng@zjnu.cn

^c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: ygy@fjirsm.ac.cn

Abstract

A layered borate Na₂B₁₀O₁₇·H₂en (1, en = ethylenediamine) with three-dimensional microporosity within the layers has been synthesized under solvothermal conditions by using organic amines and inorganic cations as the templates. Its framework displays a unique 5-connected net constructed by B₅O₁₁ cluster and emits blue luminescence.

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Article information

DOI: https://doi.org/10.1039/C5CC00800J
Article type: Communication
Submitted: 28 Jan 2015
Accepted: 13 Feb 2015
First published: 13 Feb 2015

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Chem. Commun., 2015,51, 5066-5068

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Na₂B₁₀O₁₇·H₂en: a three-dimensional open-framework layered borate co-templated by inorganic cations and organic amines

J. Wang, Q. Wei, J. Cheng, H. He, B. Yang and G. Yang, Chem. Commun., 2015, 51, 5066 DOI: 10.1039/C5CC00800J

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Chemical Communications