Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons over a MoOx/SiO2 catalyst

Fang Chen; Ning Li; Wentao Wang; Aiqin Wang; Yu Cong; Xiaodong Wang; Tao Zhang

doi:10.1039/C5CC03087K

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Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons over a MoO_x/SiO₂ catalyst†

Fang Chen,^ab Ning Li,*^ac Wentao Wang,^a Aiqin Wang,^ac Yu Cong,^a Xiaodong Wang^a and Tao Zhang*^ac

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* Corresponding authors

^a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: lining@dicp.ac.cn, taozhang@dicp.ac.cn
Fax: +86 411 84691570

^b Graduate University of Chinese Academy of Sciences, Beijing 10049, China

^c iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Abstract

For the first time, jet fuel range C₈–C₉ aromatic hydrocarbons were synthesized in high carbon yield (∼80%) by the catalytic conversion of isophorone over MoO_x/SiO₂ at atmospheric pressure. A possible reaction pathway was proposed according to the control experiments and the intermediates generated during the reaction.

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Article information

DOI: https://doi.org/10.1039/C5CC03087K
Article type: Communication
Submitted: 14 Apr 2015
Accepted: 17 Jun 2015
First published: 17 Jun 2015

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Chem. Commun., 2015,51, 11876-11879

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Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons over a MoO_x/SiO₂ catalyst

F. Chen, N. Li, W. Wang, A. Wang, Y. Cong, X. Wang and T. Zhang, Chem. Commun., 2015, 51, 11876 DOI: 10.1039/C5CC03087K

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