The first examples of organic alloys of two room temperature liquids, obtained and characterized via in situ cryo-crystallography, are presented. Thiophenol and selenophenol, which exhibit isostructurality and similar modes of S⋯S and Se⋯Se homo-chalcogen interactions along with weak and rare S–H⋯S and Se–H⋯Se hydrogen bonds, are shown to form solid solutions exhibiting Veggard's law-like trends.
S. P. Thomas, R. Sathishkumar and T. N. Guru Row, Chem. Commun., 2015, 51, 14255 DOI: 10.1039/C5CC03322E
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