Issue 62, 2015
From the journal:

Chemical Communications

Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution†

Jared B. DeCoste,*a   Matthew A. Browe,b   George W. Wagner,b   Joseph A. Rossinc  and  Gregory W. Peterson*b  

* Corresponding authors

a Leidos, Inc., PO Box 68, Edgewood Chemical Biological Center, Aberdeen Proving Ground, MD, USA
E-mail: jared.b.decoste2.ctr@mail.mil

b Edgewood Chemical Biological Center, 5183 Blackhawk Rd., Aberdeen Proving Ground, MD 21010, USA
E-mail: Gregory.w.peterson.civ@mail.mil

c Guild Associates, Inc., 5750 Shier Rings Rd., Dublin, OH, USA

Abstract

Here we report the removal of chlorine gas from air via a reaction with an amine functionalized metal–organic framework (MOF). It is found that UiO-66-NH2 has the ability to remove 1.24 g of Cl2 per g of MOF via an electrophilic aromatic substitution reaction producing HCl, which is subsequently neutralized by the MOF.

Graphical abstract: Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

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Article information

DOI
https://doi.org/10.1039/C5CC03780H
Article type
Communication
Submitted
07 May 2015
Accepted
30 Jun 2015
First published
01 Jul 2015

Chem. Commun., 2015,51, 12474-12477

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Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

J. B. DeCoste, M. A. Browe, G. W. Wagner, J. A. Rossin and G. W. Peterson, Chem. Commun., 2015, 51, 12474 DOI: 10.1039/C5CC03780H

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