Issue 99, 2015
From the journal:

Chemical Communications

Electronic vs. structural ordering in a manganese(iii) spin crossover complex†

Anthony J. Fitzpatrick,a   Eliza Trzop,b   Helge Müller-Bunz,a   Marinela M. Dîrtu,c   Yann Garcia,c   Eric Collet*b  and  Grace G. Morgan*a  

* Corresponding authors

a School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: grace.morgan@ucd.ie

b Institut de Physique de Rennes, Université de Rennes 1 UMR UR1-CNRS 6251, 35000 Rennes, France
E-mail: eric.collet@univ-rennes1.fr

c Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST) Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-neuve, Belgium

Abstract

A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long-range ordering of the NTf2− anions.

Graphical abstract: Electronic vs. structural ordering in a manganese(iii) spin crossover complex

About
Cited by
Related
Download options Please wait...

Associated articles

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC05129K
Article type
Communication
Submitted
22 Jun 2015
Accepted
19 Oct 2015
First published
19 Oct 2015

Chem. Commun., 2015,51, 17540-17543

Author version available

Download author version (PDF)

Permissions

Request permissions

Electronic vs. structural ordering in a manganese(III) spin crossover complex

A. J. Fitzpatrick, E. Trzop, H. Müller-Bunz, M. M. Dîrtu, Y. Garcia, E. Collet and G. G. Morgan, Chem. Commun., 2015, 51, 17540 DOI: 10.1039/C5CC05129K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements