Issue 80, 2015
From the journal:

Chemical Communications

Copper catalyzed sequential arylation−oxidative dimerization of o-haloanilides: synthesis of dimeric HPI alkaloids†

Xianfu Shen,a   Yongyun Zhou,a   Yongkai Xi,a   Jingfeng Zhaoa  and  Hongbin Zhang*a  

* Corresponding authors

a Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University), Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, 650091, P. R. China
E-mail: zhanghb@ynu.edu.cn
Fax: +86-871-65035538

Abstract

In this communication, we report a copper catalyzed sequential arylation−oxidative dimerization reaction as the key step for the synthesis of hexahydropyrroloindole alkaloids (+)-chimonanthine, (+)-folicanthine and (−)-calycanthine.

Graphical abstract: Copper catalyzed sequential arylation−oxidative dimerization of o-haloanilides: synthesis of dimeric HPI alkaloids

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Article information

DOI
https://doi.org/10.1039/C5CC05378A
Article type
Communication
Submitted
02 Jul 2015
Accepted
10 Aug 2015
First published
11 Aug 2015

Chem. Commun., 2015,51, 14873-14876

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Copper catalyzed sequential arylation−oxidative dimerization of o-haloanilides: synthesis of dimeric HPI alkaloids

X. Shen, Y. Zhou, Y. Xi, J. Zhao and H. Zhang, Chem. Commun., 2015, 51, 14873 DOI: 10.1039/C5CC05378A

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