Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex

Sabrina I. Kalläne; Thomas Braun; Michael Teltewskoi; Beatrice Braun; Roy Herrmann; Reik Laubenstein

doi:10.1039/C5CC05606C

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Remarkable reactivity of a rhodium(i) boryl complex towards CO₂ and CS₂: isolation of a carbido complex†

Sabrina I. Kalläne,^a Thomas Braun,*^a Michael Teltewskoi,^a Beatrice Braun,^a Roy Herrmann^a and Reik Laubenstein^a

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* Corresponding authors

^a Humboldt-Universität zu Berlin, Department of Chemistry, Brook-Taylor-Straße 2, D-12489 Berlin, Germany
E-mail: thomas.braun@chemie.hu-berlin.de

Abstract

The activation of CO₂, CS₂ as well as of PhNCO at [Rh(Bpin)(PEt₃)₃] led to C [double bond, length as m-dash] X bond cleavage and the formation of {RhXBpin} species (X = O, S, N). Treatment of the boryl complex [Rh(Bpin)(PEt₃)₃] with 0.5 equivalents of CS₂ resulted in the fragmentation of CS₂ and the formation of the remarkable μ-carbido complex trans-[Rh₂(μ-C)(SBpin)₂(PEt₃)₄].

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Article information

DOI: https://doi.org/10.1039/C5CC05606C
Article type: Communication
Submitted: 07 Jul 2015
Accepted: 07 Aug 2015
First published: 19 Aug 2015

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Chem. Commun., 2015,51, 14613-14616

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Remarkable reactivity of a rhodium(I) boryl complex towards CO₂ and CS₂: isolation of a carbido complex

S. I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann and R. Laubenstein, Chem. Commun., 2015, 51, 14613 DOI: 10.1039/C5CC05606C

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