Gold-catalyzed synthesis of buta-1,3-dien-2-yl esters by the reaction of propargyl esters with vinylazides is described; the reaction mechanism is postulated to involve a vinyl attack of vinylazides at alkenyl gold carbenes.
S. B. Wagh and R. Liu, Chem. Commun., 2015, 51, 15462 DOI: 10.1039/C5CC05945C
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