Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)–H activation

Bingxian Liu; Bin Li; Baiquan Wang

doi:10.1039/C5CC06230F

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Ru(ii)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp³)–H activation†

Bingxian Liu,^a Bin Li^a and Baiquan Wang*^abc

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* Corresponding authors

^a State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: bqwang@nankai.edu.cn
Fax: +86 (22) 23504781
Tel: +86 (22) 23504781

^b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, P. R. China

^c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides have been developed. They are the first examples of [(p-cymene)RuCl₂]₂-catalyzed C(sp³)–H bond intermolecular amidation reactions which give quinolin-8-ylmethanamines under mild reaction conditions in good yields.

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Article information

DOI: https://doi.org/10.1039/C5CC06230F
Article type: Communication
Submitted: 25 Jul 2015
Accepted: 08 Sep 2015
First published: 10 Sep 2015

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Chem. Commun., 2015,51, 16334-16337

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Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp³)–H activation

B. Liu, B. Li and B. Wang, Chem. Commun., 2015, 51, 16334 DOI: 10.1039/C5CC06230F

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