Issue 88, 2015
From the journal:

Chemical Communications

adj-Dicarbachlorin, the first free base carbaporphyrinoid system with an internal methylene unit†

Timothy D. Lash,*a   Deyaa I. AbuSalima  and  Gregory M. Ferrencea  

* Corresponding authors

a Department of Chemistry, Illinois State University, Campus Box 4160, Normal, Illinois, USA
E-mail: tdlash@ilstu.edu

Abstract

Base-catalyzed condensation of dicyclopentadienylmethane with a dipyrrylmethane dialdehyde gave a dicarbachlorin with an internal CH2 group. This unusual porphyrinoid retained highly diatropic characteristics and exhibited a porphyrin-like UV-vis spectrum.

Graphical abstract: adj-Dicarbachlorin, the first free base carbaporphyrinoid system with an internal methylene unit

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Article information

DOI
https://doi.org/10.1039/C5CC06890H
Article type
Communication
Submitted
16 Aug 2015
Accepted
09 Sep 2015
First published
10 Sep 2015

Chem. Commun., 2015,51, 15952-15955

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adj-Dicarbachlorin, the first free base carbaporphyrinoid system with an internal methylene unit

T. D. Lash, D. I. AbuSalim and G. M. Ferrence, Chem. Commun., 2015, 51, 15952 DOI: 10.1039/C5CC06890H

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