Issue 90, 2015
From the journal:

Chemical Communications

Catalytic asymmetric sulfenylation to structurally diverse dithioketals†

Kui Liao,a   Feng Zhou,*bc   Jin-Sheng Yu,a   Wei-Ming Gaoa  and  Jian Zhouad  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663N, Zhongshan Road, Shanghai 200062, China

b Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
E-mail: fzhou@chem.ecnu.edu.cn

c Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Chemical Engineering, East China Normal University, Shanghai, China

d State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, P. R. China

Abstract

We report the first example of the highly enantioselective synthesis of structurally diverse chiral dithioketals via asymmetric sulfenylation of various types of S-based nucleophiles, catalyzed by a cheap cinchona alkaloid derivative, dihydroquinine.

Graphical abstract: Catalytic asymmetric sulfenylation to structurally diverse dithioketals

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Article information

DOI
https://doi.org/10.1039/C5CC07010D
Article type
Communication
Submitted
20 Aug 2015
Accepted
11 Sep 2015
First published
14 Sep 2015

Chem. Commun., 2015,51, 16255-16258

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Catalytic asymmetric sulfenylation to structurally diverse dithioketals

K. Liao, F. Zhou, J. Yu, W. Gao and J. Zhou, Chem. Commun., 2015, 51, 16255 DOI: 10.1039/C5CC07010D

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